全文获取类型
收费全文 | 160096篇 |
免费 | 16789篇 |
国内免费 | 9333篇 |
专业分类
化学 | 81578篇 |
晶体学 | 1593篇 |
力学 | 11859篇 |
综合类 | 512篇 |
数学 | 41075篇 |
物理学 | 49601篇 |
出版年
2024年 | 100篇 |
2023年 | 1995篇 |
2022年 | 2027篇 |
2021年 | 2886篇 |
2020年 | 3875篇 |
2019年 | 3453篇 |
2018年 | 12757篇 |
2017年 | 12284篇 |
2016年 | 10030篇 |
2015年 | 4921篇 |
2014年 | 5369篇 |
2013年 | 6833篇 |
2012年 | 11606篇 |
2011年 | 18303篇 |
2010年 | 10847篇 |
2009年 | 11045篇 |
2008年 | 11990篇 |
2007年 | 13439篇 |
2006年 | 4959篇 |
2005年 | 5060篇 |
2004年 | 4387篇 |
2003年 | 4180篇 |
2002年 | 3066篇 |
2001年 | 2050篇 |
2000年 | 1887篇 |
1999年 | 1924篇 |
1998年 | 1725篇 |
1997年 | 1667篇 |
1996年 | 1706篇 |
1995年 | 1420篇 |
1994年 | 1214篇 |
1993年 | 1077篇 |
1992年 | 904篇 |
1991年 | 841篇 |
1990年 | 687篇 |
1989年 | 557篇 |
1988年 | 428篇 |
1987年 | 362篇 |
1986年 | 379篇 |
1985年 | 307篇 |
1984年 | 191篇 |
1983年 | 152篇 |
1982年 | 141篇 |
1981年 | 95篇 |
1980年 | 88篇 |
1979年 | 54篇 |
1914年 | 45篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
31.
Broadband and efficient second harmonic generation in LiNbO3-LiTaO3 composite ridge waveguides at telecom-band 下载免费PDF全文
Broadband nonlinear frequency conversions of optical waves are widely employed in multiple areas of optics and photonics. However, the broadening of conversion bandwidth is often at a cost of reduction in efficiency, which may induce a limitation on practical applications. Here we theoretically propose a novel design of LiNbO3 ridge waveguides on LiTaO3 substrates which can be used for efficient and broadband second harmonic generation. Through group velocity engineering of the ridge waveguides, acceptance bandwidth over 20 nm with a high conversion efficiency of > 25%W-1·cm-2 is achieved at telecom-band. 相似文献
32.
33.
Qiang Chenxu Hao Yuxin Zhang Wei Li Jinqiang Yang Shaowu Cao Yuteng 《应用数学和力学(英文版)》2021,42(11):1555-1570
Applied Mathematics and Mechanics - The concept of local resonance phononic crystals proposed in recent years provides a new chance for theoretical and technical breakthroughs in the structural... 相似文献
34.
Zhang Ya-Li Han Rong-Sheng Chen Liang 《International Journal of Theoretical Physics》2021,60(4):1384-1398
International Journal of Theoretical Physics - In this work, we give an analytical derivation of the reduced density matrix between two qubits in a cavity field, which is described by the quantum... 相似文献
35.
Flow, Turbulence and Combustion - The laminar flow on a curved surface transits to turbulent induced by streamline curvature which generates pressure gradient field and separated shear layer flow.... 相似文献
36.
Yang Shaoming Deng Kaiqiang Shao Shan Zhang Jian Peng Jiaxi Fang Zhili Xu Wenyuan 《Journal of Solid State Electrochemistry》2022,26(3):821-830
Journal of Solid State Electrochemistry - A molecularly imprinted photoelectrochemical (PEC) cathodic sensor was developed for the detection of bovine serum albumin (BSA). The PEC sensor was... 相似文献
37.
Taili Liu Di Zhang Md Rashedul Huqe Wen Wang Juan Antonio Zapien Sai-Wing Tsang Jingdong Luo 《中国科学:化学(英文版)》2022,65(3):584-593
The determination of nonlinearities near the band edge of organic and polymeric electro-optic(EO)materials is important from the viewpoint of molecular nonlinear optics(NLO)and photonic device applications.Based on transmission-mode Stark effect electromodulation(EM)spectroscopy,we study the electric-field-induced changes in optical absorption and refraction of newly developed EO polymers from the visible to near-infrared(NIR)wavelengths and report record-high near-band-edge complex EO effects from poled thin films.Values ofΔn andΔk up to 10-3 and 10-2 are found at an applied electric field of 2.0×105-3.0×105V/cm.The study of linear optical properties of poled films by spectroscopic ellipsometry shows large polinginduced birefringence and a nearly two-fold increase in the extinction coefficients at the extraordinary polarization.Through the Kramers-Kronig analysis,we obtained the real and imaginary second-order nonlinear coefficients up to~3,500 and~5,600 pm/V,respectively,which are believed to be the highest NLO coefficients of poled polymers through the resonance enhancement.Our approach goes beyond the previous works,applicable only to several discrete wavelengths,to a full-spectral analysis with independent verification of slab waveguide measurements.By considering both the electroabsorption and electrorefraction effects,our study overcomes the limitation of the classic qualitative two-level model and provides a quantitative understanding of near-resonance optical nonlinearities of organic EO materials.It can inspire the exploration of high-speed,absorptive,or phase-shifting light-modulators using EO polymers for on-chip applications. 相似文献
38.
System scan of the multiplicity correlation between forward and backward rapidities in relativistic heavy-ion collisions using a multi-phase transport model 下载免费PDF全文
A systematic study on forward–backward (FB) multiplicity correlations from large systems to small ones through a multi-phase transport model (AMPT) has been performed and the phenomenon that correlation strength increases with centrality can be explained by taking the distribution of events as the superposition of a series of Gaussian distributions. It is also found that correlations in the \begin{document}$ \eta -\phi $\end{document} ![]()
![]()
plane can imply the shape of the event. Furthermore, long-range correlations originate from the fluctuations associated with the source information. FB correlations allow us to decouple long-range correlations from short-range correlations, and may provide a chance to investigate the α-clustering structure in initial colliding light nuclei as well. It seems the tetrahedron 16O + 16O collision gives a more uniform and symmetrical fireball, that emits the final particles more isotropically or independently in the longitudinal direction, indicating that the forward–backward multiplicity correlation could be used to identify the pattern of α-clustered 16O in future experiments. 相似文献
39.
化学工业生产中,用氢气为还原剂,通过选择性加氢可以制备多种重要化学品。5-羟甲基糠醛是重要的生物质基平台化合物,而5-甲基糠醛是用途广泛的化学品。由5-羟甲基糠醛加氢得到5-甲基糠醛是一条非常理想的路径,但是选择性活化C-OH非常困难。本文设计并制备了Pt@PVP/Nb2O5(PVP: 聚乙烯吡咯烷酮)催化剂,该催化体系巧妙地结合了位阻效应、氢溢流和催化剂界面的电子效应,系统研究了该催化剂对5-羟甲基糠醛选择性加氢制备5-甲基糠醛催化性能,在最优条件下,5-甲基糠醛的选择性可达92%。利用密度泛函理论计算研究了5-羟甲基糠醛选择性加氢制备5-甲基糠醛反应路径。 相似文献
40.
Yi-Tong Xu Tian-Yang Zhang Zheng Li Xiang-Nan Liu Yuan-Cheng Zhu Wei-Wei Zhao Hong-Yuan Chen Jing-Juan Xu 《Electroanalysis》2022,34(6):947-955
Photoelectrochemical (PEC) cytosensors, a combination of the PEC process and the living-cell assay, have emerged as a powerful tool in the analytical and biological science. This mini review provides a brief introduction of this arena and summaries the key steps about the development of PEC cytosensors with representative examples, followed by future prospects based on our own opinions. 相似文献